Hydrogeochemical Assessment of Groundwater in Epe (Nigeria) for Drinking and Irrigation Purposes
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Abstract
Groundwater sustainability demands routine quality monitoring. This study assessed the hydrogeochemistry of groundwater in Epe, Lagos State, to evaluate its suitability for drinking and irrigation. Fifty well-water samples from eight communities were analyzed for pH and major ions. Results showed that parameters complied with regulatory standards in most locations except magnesium (65.70±23.50 - 96.00±19.68 mg/L) which consistently exceeded the Nigerian Standard for Drinking Water Quality of 20 mg/L. Dietary intake of essential elements was generally negligible, though magnesium levels in Poka exceeded recommended daily allowance for infants (0-6 months). The Water Quality Index (40.41 - 128.49) classified the water as 8% “excellent,” 76% "good," and 16% "poor" while the Pollution Index of Groundwater (0.39 - 0.85) ranked all samples as having insignificant pollution. Though, majority of the irrigation indices indicated suitability for irrigation; Permeability Index (<25% in 88% of samples), Magnesium Adsorption Ratio (>50% in 86% samples) and Corrosivity Ratio (>1 in 50% samples) presented risks to long-term soil permeability and metallic water transport pipes. The ionic dominance was Mg²⁺>Ca²⁺>Na⁺>K⁺ and HCO₃⁻>SO₄²⁻>Cl⁻. Geochemical diagrams (Piper, Chadha and Schoeller diagrams) revealed a Ca-Mg-HCO₃ facies, attributed to mixed carbonate-silicate weathering (Gaillardet diagram), rock-water interaction (Gibb’s diagram) and ion exchange (CAI, CAII), with the Hydrochemical Facies Evolution Diagram indicating mixed facies. Principal Component Analysis identified bicarbonate (PC1: 57.33%), calcium (PC2: 17.35%), sulphate (PC3: 15.94%) and magnesium (PC4: 8.38%) as the primary factors controlling water quality. The study recommends water treatment, the use of corrosion-resistant pipes, and sustained monitoring to safeguard this resource.
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Copyright (c) 2026 Benjamin Onozeyi Dimowo, Adewole Michael Gbadebo, Kudirat Akorede Otubu, Oluwajumilo Oluwadara Gbadebo (Author)

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Adewole Michael Gbadebo, Department of Bioscience, University of East London, London, United Kingdom.
Professor of Environmental Geology/Geochemistry, Department of Geology
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